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pneumoniae , a Mn-centric bacterium, 110 Zn II is an inhibitor of Mn II uptake by the ATP-binding cassette (ABC) transporter, PsaBCA, 106 where it forms a coordination complex that is very nearly isostructural with that of Mn II , but fails to transport Zn II across the pneumococcal membrane, thus inducing cellular Mn II starvation

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It just happens naturally. References Turner, E
